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Title Chiral diazaligands for asymmetric synthesis / volume editors, Marc Lemaire, Pierre Mangeney ; with contributions by J.A.J. Breuzard [and others].
Imprint Berlin ; New York : Springer, 2005.

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Series Topics in organometallic chemistry ; v. 15
Topics in organometallic chemistry ; v. 15.
Subject Asymmetric synthesis.
Enantioselective catalysis.
Ligands (Biochemistry)
Alt Name Lemaire, Marc.
Mangeney, Pierre.
Breuzard, J. A. J. (Jérémy A. J.)
Description 1 online resource (viii, 301 pages) : illustrations.
polychrome rdacc
Bibliography Note Includes bibliographical references and indexes.
Contents Progress in the asymmetric synthesis of 1,2-diamines from azomethine compounds / D. Savoia -- Sparteine as a chiral ligand for asymmetric catalysis / O. Chuzel [and others] -- Use of N, N-coordinating ligands in catalytic asymmetric C--C bond formations, example of cyclopropanation, diels--alder reaction, nucleophilic allylic substitution / E. Schulz -- Non-covalent immobilization of catalysts based on chiral diazaligands / J.M. Fraile [and others] -- Chiral diaminocarbene complexes, synthesis and application in asymmetric catalysis / S. Roland [and others] -- Chiral ureas and thiroureas in asymmetric catalysis / J.A.J. Breuzard [and others] -- Chiral-at-metal complexes as asymmetric catalysts / M. Fontecave [and others].
Summary The use of phosphine derivatives has historically induced the tremendous development of catalysis (both non-asymmetric and asymmetric). Although the chemistry of amines is more documented, the use of nitrogen-containing ligands only appeared recently. Nevertheless, during the last ten years, the results describing chiral diamine preparations and their uses in asymmetric catalysis and synthesis are increasing faster than their phosphorus counterparts. The reader will find in this volume the most recent methods for the synthesis of chiral diamines as well as their applications in asymmetric catalysis of CC bond formation. Particular attention will be given to spartein and derivatives of such diamines. Recently, the particular properties and the chemistry of amines allowed to obtain catalysts easy to separate and recycle and new types of ligands such as diaminocarbenes, ureas and thioureas. Finally, the complexing properties of some diamines allowed the formation of complexes with chirality "at the metal " which is of major theoretical interest and presents numerous potential applications.
Note Print version record.
ISBN 9783540314424
9783540260646 (acid-free paper)
3540260641 (acid-free paper)
ISBN/ISSN 10.1007/b105252
OCLC # 262681320
Additional Format Print version: Chiral diazaligands for asymmetric synthesis. Berlin ; New York : Springer, 2005 3540260641 9783540260646 (DLC) 2005933266 (OCoLC)61703238

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